Palladium-Catalyzed Carboxylative Coupling of Allylstannanes and allyl halides

Authors

Russell J. Franks, Stephen F Austin State UniversityFollow

Document Type

Article

Publication Date

2000

Abstract

A three-component carboxylative coupling between allyl halides, allylstannanes, and CO2 to produce allyl esters is catalyzed by Pd and Pt phosphine complexes. Allyl chloride and allyltributylstannane are thus converted to propenyl butenoate in excellent yield. Cross coupling of two different allyl components produces a nearly statistical mixture of all four possible esters. Tentative mechanistic pathways for the catalytic reaction are proposed.

Comments

Franks, Russell J., and Kenneth M. Nicholas. "Palladium-catalyzed carboxylative coupling of allylstannanes and allyl halides." Organometallics 19, no. 8 (2000): 1458-1460.

Archived with permission from the American Chemical Society.

Repository Citation

Franks, Russell J., "Palladium-Catalyzed Carboxylative Coupling of Allylstannanes and allyl halides" (2000). Faculty Publications. 30.
https://scholarworks.sfasu.edu/chemistry_facultypubs/30