Singlet molecular oxygen [1O2 (1Δg)] is generated cleanly in aqueous solution upon irradiation of a heterogeneous complex, meso-tetra(N-methyl-4-pyridyl)porphine (1) adsorbed onto porous Vycor glass (PVG). The cationic photosensitizer 1 tightly binds onto PVG and gives a stable material, which does not dissociate 1 into the surrounding aqueous phase. The production of 1O2 was measured by monitoring the time-resolved 1O2 (1Δg) phosphorescence at 1270 nm. Indirect analysis of 1O2 generation was also carried out with the photooxidation oftrans-2-methyl-2-pentenoate anion, which afforded the corresponding hydroperoxide. Sensitizer-1-impregnated PVG gives rise to a new singlet oxygen generator but more importantly provides a heterogeneous system for use in water.
Aebisher, David; Azar, Nikolay S.; Zamadar, Matibur; Gandra, Naveen; Gafney, Harry D.; Gao, Roumei; and Greer, Alexander, "Singlet Oxygen Chemistry in Water: A Porous Vycor GlassSupported Photosensitizer" (2008). Faculty Publications. Paper 29.
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